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The ability of thiosemicarbazones to form stable complexes with transition metal ions makes them versatile pharmacophores. Indeed, diverse thiosemicarbazones have been explored as antiviral, antifungal, antibacterial and antitumoral agents [ 1 , 2 ]. Inherent in the design of the thiosemicarbazone is the ability to form metal complexes with transition state metals such as iron, copper and zinc [ 1 ]. Metal binding affinity and antitumor activity varies with each individual compound and mechanistic differences have been noted based on whether iron or copper is the preferred chelation partner. Both are redox-active metals with the potential for reactive oxygen species ROS generation [ 2 ]. Thus, intracellular delivery of redox-active transition metals can be used to alter redox homeostasis for therapeutic benefit [ 3 ].

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